π Key Points
- Carbon valency: Always 4. Forms 4 covalent bonds (single, double, or triple)
- Catenation: Ability of carbon to bond with itself, forming long stable chains and rings
- Hydrocarbons: Compounds containing only C and H atoms. Classified by bond type
- Alkanes: CβHββββ, single bonds only, saturated, less reactive, general formula CβHββββ
- Alkenes: CβHββ, contain C=C double bond, unsaturated, more reactive, undergo addition
- Alkynes: CβHββββ, contain Cβ‘C triple bond, highly unsaturated and reactive
- Saturated compounds: Only single bonds, less reactive, higher melting/boiling points
- Unsaturated compounds: Double or triple bonds, more reactive, can undergo addition reactions
- Functional groups: -OH (alcohol), -CHO (aldehyde), -COOH (carboxylic acid), -CO- (ketone)
- Isomers: Same molecular formula, different structural arrangements, different properties
- Combustion: CβHββ + Oβ β COβ + HβO + Heat (complete) or CO + C + HβO (incomplete)
- Complete combustion: Blue flame, produces COβ + HβO, maximum energy released
- Incomplete combustion: Yellow flame, produces CO + soot + HβO, less energy, toxic CO
- Diamond: 3D tetrahedral network, hardest, transparent, non-conductor
- Graphite: Layered structure, soft, black, conducts electricity, free Ο-electrons
- Allotropes of carbon: Same element, different structures (diamond, graphite, fullerenes) = different properties
- Boiling point trend: Increases with chain length (~20K per CHβ) due to van der Waals forces
- IUPAC nomenclature: Prefix (C number) + Root (bond type) + Suffix (functional group)
- C-C bond length: Single (154 pm) > Double (134 pm) > Triple (120 pm)
- Structural isomerism: Different arrangement of atoms. Positional isomerism: Functional group at different position
π Important Definitions
β οΈ Common Mistakes
β Wrong: Carbon has variable valency like other elements.
β Correct: Carbon valency is ALWAYS 4. It forms different types of bonds (single, double, triple) but always totaling 4 bonds.
β Wrong: Saturated compounds are 'full of bonds' so they are most stable.
β Correct: Saturated means SINGLE BONDS ONLY. Unsaturated (double/triple bonds) are MORE reactive because multiple bonds can break and add other atoms.
β Wrong: All isomers have the same properties.
β Correct: Isomers have SAME molecular formula but DIFFERENT structures and DIFFERENT properties (boiling point, reactivity, etc.).
β Wrong: Diamond is soft and graphite is hard because of different elements.
β Correct: Both are carbon allotropes! Diamond is HARD (3D network), graphite is SOFT (layered). Structure determines property, not composition.
β Wrong: Complete combustion produces CO and water.
β Correct: Complete combustion (sufficient Oβ) produces COβ and HβO. CO is produced only in INCOMPLETE combustion (limited Oβ).
β Wrong: Functional groups don't affect compound properties much.
β Correct: Functional groups DETERMINE properties! Same carbon skeleton with different functional groups = completely different compounds with different properties.
π Exam Focus
These questions are frequently asked in CBSE exams:
π― Last-Minute Recall
Close your eyes and try to recall: Key definitions, formulas, and 3 common mistakes. If you can recall 80% without looking, you're exam-ready!