📌 Key Points
- Acids produce H⁺ (H₃O⁺) ions in water; bases produce OH⁻ ions in water
- Litmus: acid → red, base → blue. Phenolphthalein: acid → colourless, base → pink
- Acid + Metal → Salt + H₂↑ (pop sound test). Acid + Metal carbonate → Salt + H₂O + CO₂↑ (lime water turns milky)
- Acid + Base → Salt + Water (neutralisation, exothermic)
- Metal oxides are basic; non-metal oxides are acidic
- Dry HCl does not show acidic behaviour — water is essential to produce H⁺ ions
- Always add acid to water (never water to acid) — dilution is highly exothermic
- pH scale: 0–14. pH < 7 = acidic, pH 7 = neutral, pH > 7 = basic
- Tooth enamel corrodes below pH 5.5. Bee sting = acidic (use baking soda). Wasp sting = basic (use vinegar)
- Chlor-alkali process: 2NaCl + 2H₂O → 2NaOH + Cl₂ + H₂ (electrolysis of brine)
- Bleaching powder: Ca(OH)₂ + Cl₂ → CaOCl₂ + H₂O
- Baking soda = NaHCO₃ (antacid, baking). Washing soda = Na₂CO₃·10H₂O (cleaning, softening hard water)
- Plaster of Paris: CaSO₄·½H₂O (from gypsum CaSO₄·2H₂O at 373 K). Sets back to gypsum on adding water
- CuSO₄·5H₂O (blue) → CuSO₄ (white) on heating. Blue returns on adding water
- Strong acids (HCl, H₂SO₄, HNO₃) fully ionise. Weak acids (CH₃COOH, H₂CO₃) partially ionise
📘 Important Definitions
🔢 Formulas & Laws
Acid + Metal
2HCl + Zn → ZnCl₂ + H₂↑
H₂ burns with a pop sound
Acid + Metal carbonate
2HCl + Na₂CO₃ → 2NaCl + H₂O + CO₂↑
CO₂ turns lime water milky
Chlor-alkali process
2NaCl + 2H₂O → 2NaOH + Cl₂ + H₂
Electrolysis of brine
Plaster of Paris preparation
CaSO₄·2H₂O →(373K) CaSO₄·½H₂O + 1½H₂O
Gypsum → POP
Setting of POP
CaSO₄·½H₂O + 1½H₂O → CaSO₄·2H₂O
POP + water → gypsum (hard)
⚠️ Common Mistakes
✗ Wrong: Saying 'acid turns litmus red'
✓ Correct: Be specific: acid turns BLUE litmus red. Red litmus shows no change in acid.
✗ Wrong: Confusing NaHCO₃ (baking soda) with Na₂CO₃ (washing soda)
✓ Correct: NaHCO₃ = baking soda (hydrogen carbonate). Na₂CO₃·10H₂O = washing soda (carbonate with 10H₂O).
✗ Wrong: Writing CaSO₄ as the formula of plaster of Paris
✓ Correct: POP is CaSO₄·½H₂O (hemihydrate). Gypsum is CaSO₄·2H₂O (dihydrate). Anhydrous CaSO₄ is different.
✗ Wrong: Adding water to concentrated acid during dilution
✓ Correct: Always add acid to water slowly. Adding water to acid causes violent spattering due to extreme heat.
✗ Wrong: Mixing up bee sting and wasp sting treatment
✓ Correct: Bee = acidic → apply baking soda (base). Wasp = basic → apply vinegar (acid). B→B, W→V.
📝 Exam Focus
These questions are frequently asked in CBSE exams:
Diagram to practice: Practice drawing: pH scale with colours, chlor-alkali process setup, electrolysis of brine, reaction of acid with metal/carbonate apparatus
🎯 Last-Minute Recall
Close your eyes and try to recall: Key definitions, formulas, and 3 common mistakes. If you can recall 80% without looking, you're exam-ready!